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Observed (measured) Mass of Atoms
Mass spectroscopy is used to determine the mass of the isotopes of an element3.
The observed mass, the mass observed using mass spectroscopy, of some isotopes is given in the table below in "atomic mass units" and in the SI units of kilograms (kg):
Element Name |
Atomic Number |
Isotope Symbol |
Mass atomic mass units |
Mass kg |
hydrogen |
1 |
1H |
1.007 |
1.674 × 10-27 |
2H |
2.014 |
3.344 × 10-27 |
3H |
3.016 |
5.008 × 10-27 |
helium |
2 |
3He |
3.016 |
5.008 × 10-27 |
4He |
4.003 |
6.646 × 10-27 |
lithium |
3 |
6Li |
6.015 |
9.988 × 10-27 |
7Li |
7.016 |
1.165 × 10-26 |
You will find a more complete list of the observed mass of isotopes at the bottom of this page.
Predicting the Mass of an Atom of an Isotope of an Element
An atom is made up of a number of electrons surrounding a nucleus containing a number of protons and neutrons.
The protons and neutrons in a nucleus are referred to as nucleons.
An isotope of an element with the chemical symbol E and a mass number A and an atomic number Z can be written in one of two ways:
where:
Z = atomic number (given in Periodic Table)
= number of protons in the nucleus of the atom
A = mass number (given in isotope's name/symbol)
= number of protons plus number of neutrons
Therefore we can calculate the number of neutrons in the nucleus of the atom:
number of neutrons = mass number - atomic number
number of neutrons = A - Z
The number of negatively charged electrons surrounding the nucleus of a neutral atom, that is an atom with no overall charge, equals the number of positively charged protons in the nucleus, so:
Number of electrons in the neutral atom
= number of protons in nucleus
= atomic number
= Z
Each of these subatomic particles (protons, neutrons and electrons) has a rest mass.
The rest mass of protons, neutrons and electrons is usually given to you on a data sheet.
These masses given below are in "atomic mass units" and in the SI units of mass, kilograms (kg):
Subatomic Particle |
Rest Mass atomic mass units |
Rest Mass kg |
proton |
1.007276 |
1.673 × 10-27 |
neutron |
1.008665 |
1.675 × 10-27 |
electron |
0.000549 |
9.109 × 10-31 |
We can use the information provided in the symbol for the isotope along with the information supplied in the table above to calculate the predicted mass of an isotope of the element:
predicted mass of atom |
= |
mass of all protons |
+ |
mass of all neutrons |
+ |
mass of all electrons |
|
= |
(Z × mass proton) |
+ |
([A − Z] × mass neutron) |
+ |
(Z × mass electron) |
For example, we can calculate the predicted mass of an atom of hydrogen-1, 1H, in kilograms:
Symbol for this hydrogen isotope is |
1 |
H |
1 |
No. protons = atomic number (Z)
No. protons = 1 (from Periodic Table)
No. neutrons = mass number (A) - atomic number (Z)
No. neutrons = 1 - 1 = 0
(mass number given in the question, 1H)
No. electrons in the neutral atom = atomic number (Z)
No. electrons = 1
mass of a proton = mp = 1.673 × 10-27 kg
mass of a neutron = mn = 1.675 × 10-27 kg
mass of an electron = me = 9.109 × 10-31 kg
predicted mass 1H atom in kg |
= |
(Z × mp) |
+ |
([A − Z] × mn) |
+ |
(Z × me) |
= |
(1 × 1.673 × 10-27) |
+ |
([1 − 1] × 1.675 × 10-27) |
+ |
(1 × 9.109 × 10-31) |
= |
1.673 × 10-27 |
+ |
0 |
+ |
9.109 × 10-31 |
= |
1.674 × 10-27 kg |
|
|
|
|
Similarly we can predict the mass of an atom of deuterium, the hydrogen-2 or 2H isotope, in kilograms:
Symbol for this hydrogen isotope is |
2 |
H |
1 |
No. protons = atomic number (Z)
No. protons = 1 (from Periodic Table)
No. neutrons = mass number (A) - atomic number (Z)
No. neutrons = 2 - 1 = 1
(mass number given in the question, 2H)
No. electrons in the neutral atom = atomic number (Z)
No. electrons = 1
mass of a proton = mp = 1.673 × 10-27 kg
mass of a neutron = mn = 1.675 × 10-27 kg
mass of an electron = me = 9.109 × 10-31 kg
predicted mass of 2H atom in kg |
= |
(Z × mp) |
+ |
([A − Z] × mn) |
+ |
(Z × me) |
= |
(1 × 1.673 × 10-27) |
+ |
([2 − 1] × 1.675 × 10-27) |
+ |
(1 × 9.109 × 10-31) |
= |
1.673 × 10-27 |
+ |
1.675 × 10-27 |
+ |
9.109 × 10-31 |
= |
3.349 × 10-27 kg |
|
|
|
|
We can also predict the mass of an atom of an isotope of an element in "atomic mass units" if required.
For example, we can predict the mass of the deuterium, hydrogen-2 or 2H, atom in "atomic mass units":
No. protons = atomic number (Z)
No. protons = 1 (from Periodic Table)
No. neutrons = mass number (A) - atomic number (Z)
No. neutrons = 2 - 1 = 1
(mass number given in the question, 2H)
No. electrons in the neutral atom = atomic number (Z)
No. electrons = 1
mass of a proton = mp = 1.007276 u
mass of a neutron = mn = 1.008665 u
mass of an electron = me = 0.000549 u
predicted mass of 2H atom in atomic mass units |
= |
(Z × mp) |
+ |
([A − Z] × mn) |
+ |
(Z × me) |
= |
(1 × 1.007276) |
+ |
([2 − 1] × 1.008665) |
+ |
(1 × 0.000549) |
= |
1.007276 |
+ |
1.008665 |
+ |
0.000549 |
= |
2.01649 u |
|
|
|
|
Mass Conversions: kilograms and atomic mass units
The SI unit of mass is the kilogram, kg, which is an incredibly huge unit to use when talking about the mass of an atom.
As we discovered above, the mass of an atom of hydrogen-1 is found to be 1.674 × 10-27 kg.
Physicists often prefer to work in "atomic mass units", u, rather than kilograms, kg.
Since the mass of an atom is its mass relative to an atom of the carbon-12 atom, and the mass of the carbon-12 atom is defined as 12.000 000 atomic mass units (12.000 000 u),
then 1 atomic mass unit = 1/12 the mass of the carbon-12 atom.
The mass of the carbon-12 atom has been determined to be 1.993 × 10-26 kg
1 atomic mass unit = 1/12 × 1.993 × 10-26 = 1.661 × 10-27 kg
So if the mass of the hydrogen-1 atom has been given in atomic mass units as 1.007 u, we can convert this to a mass in kilograms by multiplying by 1.661 × 10-27:
mass 1H = 1.007 u
mass 1H = 1.007 u × 1.661 × 10-27 kg/u
= 1.673 kg
If the mass of the hydrogen-2 atom has been given as 3.344 × 10-27 kg we can convert this to atomic mass units by dividing by 1.661 × 10-27:
mass 2H = 3.344 × 10-27 kg
mass 2H = 3.344 × 10-27 kg ÷ 1.661 × 10-27 kg/u
= 2.013 u
Mass Defect
Compare the values for the predicted mass of the atom of each isotope of hydrogen we calculated above, with its observed (measured) value from the table in the first section above:
hydrogen isotope |
predicted mass / kg |
observed mass /kg |
1H |
1.674 × 10-27 |
1.674 × 10-27 |
2H |
3.349 × 10-27 |
3.344 × 10-27 |
For the hydrogen-1 isotope, 1H, the predicted mass and the observed mass are the same.
However, the mass we predicted for an atom of the deuterium isotope, 2H, is greater than the mass observed when scientists measure the mass of the deuterium atom.
In fact, with the exception of 1H, the predicted mass of an atom based on calculations of the total mass of protons, neutrons and electrons it contains is always greater than the mass of the atom when it is measured!
This difference between predicted and observed mass of an atom is called the mass defect.
Mass defect is usually given the symbol Δm (to represent an observable change in mass), and the mass of an atom is usually given the symbol M (or Mr for relative atomic mass).
mass defect |
= |
predicted mass |
- |
observed mass |
Δm |
= |
(Z × mass of proton) |
+ |
([A-Z] × mass of neutron) |
+ |
(Z × mass of electron) |
- |
M |
Δm |
= |
(Z × mp) |
+ |
([A-Z] × mn) |
+ |
(Z × me) |
- |
M |
We can calculate the mass defect for an atom of the 2H isotope in kilograms as:
observed mass = 3.344 × 10-27 kg (from table)
predicted mass = 3.349 × 10-27 kg (calculated above)
mass defect |
= |
predicted mass |
- |
observed mass |
Δm |
= |
3.349 × 10-27 |
- |
3.344 × 10-27 |
|
= |
5 × 10-30 kg |
|
|
Similarly we can calculate the mass defect for the 2H atom in "atomic mass units" (u):
observed mass = 2.014 u (from table)
predicted mass = 2.016 u (calculated above)
mass defect |
= |
predicted mass |
- |
observed mass |
Δm |
= |
2.016 |
- |
2.014 |
|
= |
0.002 u |
|
|
The mass defect can be used to calculate the nuclear binding energy and hence explain the stability of certain isotopes.