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Structural Isomers of Alkenes

Key Concepts

Structural isomers are molecules with:
  • same molecular formula

  • different structural formulae

Structural isomers of alkenes have:

  • same number of atoms of carbon and hydrogen

  • different arrangement of carbon and hydrogen atoms

Animated Tutorial

Examples

1-butene has the molecular formula C4H8.
All possible structural isomers of 1-butene must have the molecular formula C4H8.
name structural formula molecular formula
1-butene
  H
|
      H
|
  H
|
 
  C = C - C - C -H
  |
H
  |
H
  |
H
  |
H
 
C4H8

2-butene
  H
|
          H
|
 
H- C - C = C - C -H
  |
H
  |
H
  |
H
  |
H
 
C4H8

2-methylpropene
  H
|
      H
|
 
  C = C - C -H
  |
H
  |
H-C-H
  |
H
 
      |
H
     
C4H8

cyclobutane
  H
|
  H
|
 
H- C - C -H
  |   |  
H- C - C -H
  |
H
  |
H
 
C4H8


1-butene, 2-butene, 2-methylpropene and cyclobutane are structural isomers.
They have the same molecular formula, C4H8, but different structural formulae.
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Related AUS-e-TUTE Topics

Summary of Nomenclature

Naming Straight Chain Alkanes

Naming Branched Chain Alkanes

Naming Simple Alkenes

Naming Simple Alkynes

Naming Structural Isomers of Alkanes

Naming Alkanols

Naming Haloalkanes

Carboxylic (alkanoic) Acids

Amines

Functional Groups

Combustion of Hydrocarbons

Halogenation of Hydrocarbons

Hydrohalogenation of Unsaturated Hydrocarbons

Hydration of Alkenes to Alkanols

Preparation and Naming of Polymers (Polymerization)

 
 

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