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Combustion of Hydrocarbons

Key Concepts

Complete Combustion of hydrocarbons:

  • Excess O2(g) is present to react.

  • Reaction products are CO2(g) and H2O(g).

  • Hydrocarbon combusts (burns) with a clean flame.

Incomplete Combustion of hydrocarbons:

  • Insufficient O2(g) is present, that is, there is excess hydrocarbon present.
        O2(g) is the limiting reagent in the reaction.

  • Reaction products are either CO(g) and/or C(s) and H2O(g).

  • Hydrocarbon combusts (burns) with a smokey or sooty flame.

Animated Tutorial

Example of Complete Combustion

Methane, CH4(g), a common component of natural gas, combusts in excess oxygen to produce carbon dioxide gas and water vapour.
Write a balanced chemical equation to represent the complete combustion of methane gas.

  1. Write the word equation for the complete combustion of methane:
    general equation: reactants products
    word equation: methane + oxygen gas carbon dioxide gas + water vapour

  2. Write the formula for each reactant and product in the word equation:
    Reactants   Products
    methane :

    oxygen gas :

    CH4(g)

    O2(g)

      carbon dioxide gas :

    water vapour :

    CO2(g)

    H2O(g)

  3. Write the unbalanced chemical equation by substituting the formula for the name of each reactant and product in the word equation:
    word equation : methane + oxygen gas carbon dioxide gas + water vapour
    unbalanced chemical equation : CH4(g) + O2(g) CO2(g) + H2O(g)

  4. Balance the chemical equation:
    unbalanced chemical equation : CH4(g) + O2(g) CO2(g) + H2O(g)
    No. C atoms : 1 = 1 C atoms balanced
    No. H atoms :   4   2 H atoms NOT balanced
    Need to multiply the number of water molecules by 2 to balance the hydrogen atoms.
    CH4(g) + O2(g) CO2(g) + 2H2O(g)
    No. C atoms : 1 = 1 C atoms balanced
    No. H atoms :   4 =   4 H atoms balanced
    No. O atoms : 2   2 +     2 O atoms NOT balanced
    Need to multiply the number of oxygen molecules by 2 to balance the oxygen atoms.
    CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
    No. C atoms : 1 = 1 C atoms balanced
    No. H atoms :   4 =   4 H atoms balanced
    No. O atoms : 4 =   2 +     2 O atoms balanced

  5. The balanced chemical equation for the complete combustion of methane gas is:
    CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)

Example of Incomplete Combustion

In a particular experiment, excess methane was combusted in limited oxygen to produce soot (solid carbon) and water vapour.
Write a balanced chemical equation to represent the incomplete combustion of methane in this experiment.

  1. Write the word equation for the incomplete combustion of methane:
    general equation: reactants products
    word equation: methane + oxygen gas solid carbon + water vapour

  2. Write the formula for each reactant and product in the word equation:
    Reactants   Products
    methane :

    oxygen gas :

    CH4(g)

    O2(g)

      solid carbon :

    water vapour :

    C(s)

    H2O(g)

  3. Write the unbalanced chemical equation by substituting the formula for the name of each reactant and product in the word equation:
    word equation : methane + oxygen gas solid carbon + water vapour
    unbalanced chemical equation : CH4(g) + O2(g) C(s) + H2O(g)

  4. Balance the chemical equation:
    unbalanced chemical equation : CH4(g) + O2(g) C(s) + H2O(g)
    No. C atoms : 1 = 1 C atoms balanced
    No. H atoms :   4   2 H atoms NOT balanced
    Need to multiply the number of water molecules by 2 to balance the hydrogen atoms.
    CH4(g) + O2(g) C(s) + 2H2O(g)
    No. C atoms : 1 = 1 C atoms balanced
    No. H atoms :   4 =   4 H atoms balanced
    No. O atoms : 2 =     2 O atoms balanced

  5. The balanced chemical equation for the incomplete combustion of methane gas in this experiment is :
    CH4(g) + O2(g) → C(s) + 2H2O(g)
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Related AUS-e-TUTE Topics

Summary of Nomenclature

Naming Straight Chain Alkanes

Naming Branched Chain Alkanes

Naming Simple Alkenes

Naming Simple Alkynes

Naming Structural Isomers of Alkanes

Naming Structural Isomers of Alkenes

Naming Alkanols

Naming Haloalkanes

Functional Groups

Halogenation of Hydrocarbons

Hydrohalogenation of Unsaturated Hydrocarbons

Hydration of Alkenes to Alkanols

Oxidation of Alkanols

Dehydration of Alkanols (alcohols)

Preparation and Naming of Esters (Esterification)

Substitution Reactions of Haloalkanes (alkyl halides)

Preparation and Naming of Polymers (Polymerization)

Properties and Uses of Alkanes

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Properties and Uses of Polythene (polyethylene)

 
 

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